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JEE Advanced levelSingle correct optionDifficulty 3 of 3pl273

A short fragment of a polymer chain (end groups shown) is drawn. Which of the structures shown, given as two molecules, are the products of complete hydrolysis of all carbonate links?

  1. AStructure A
  2. BStructure B
  3. CStructure C
  4. DStructure D

Answer: B

The links are carbonate groups, -O-CO-O-, in poly(propylene carbonate), made from propylene oxide and carbon dioxide. Hydrolysis of each carbonate gives two alcohol groups and carbon dioxide (via carbonic acid). The diol unit is propane-1,2-diol, so the products are propane-1,2-diol and carbon dioxide. The other options have the wrong diol or the wrong one-carbon product.
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