JEE Advanced levelSingle correct optionDifficulty 3 of 3pl146
A Buna-N sample is made from acrylonitrile (CHX2=CH−CN, 53) and buta-1,3-diene (CX4HX6, 54) and contains 8.70% nitrogen by mass (N 14). The mole ratio of acrylonitrile to butadiene units is
A1:2
B1:1
C2:1
D1:3
Answer: A
Let the ratio be x:1. N percent =14x/(53x+54)×100. For x=1/2: 7/(26.5+54)=7/80.5=8.70%. The ratio 1:1 would give 13.1% and 1:3 would give 6.5%.