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Molecular mass of polymers
JEE Main level
Single correct option
Difficulty 2 of 3
pl141
Equal masses (50 g each) of two monodisperse fractions of molar mass
10000
and
40000
g
mo
l
−
1
are mixed. The number-average molar mass in
g
mo
l
−
1
is
A
20000
B
16000
C
32000
D
25000
Answer: B
M
n
= total mass/total moles
=
100/
(
50/10000
+
50/40000
)
=
100/
(
0.00500
+
0.00125
)
=
16000
. The value
25000
is
M
w
(mass-weighted mean).
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