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JEE Main levelSingle correct optionDifficulty 2 of 3pl127

In the free radical addition polymerisation of a vinyl monomer, the initiation step involves

  1. Aheterolytic cleavage of the initiator to give ions that add to the monomer
  2. Bnucleophilic attack of an organometallic compound on the monomer
  3. Chomolytic cleavage of the initiator (for example benzoyl peroxide) to give free radicals that add to the monomer
  4. Dprotonation of the monomer by a strong acid

Answer: C

Benzoyl peroxide on heating splits homolytically at the O-O bond into radicals. These radicals add to the C=C of a monomer to start the chain.
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