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JEE Main levelSingle correct optionDifficulty 2 of 3pl081

In vulcanisation of polyisoprene, sulfur cross-links are believed to attach mainly at

  1. Athe allylic carbon atoms next to the bonds
  2. Bthe carbonyl carbons of the chain
  3. Cthe chain-end hydroxyl groups only
  4. Dcarbon atoms far from any double bond, because these are the most reactive

Answer: A

Polyisoprene has bonds, and the allylic positions beside them are the reactive sites where sulfur bridges form. The chain contains no carbonyl or hydroxyl groups.
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