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JEE Main levelSingle correct optionDifficulty 2 of 3pl062

Which statement about novolac, the first-stage product in one route to bakelite, is correct?

  1. AIt is made with excess formaldehyde under basic catalysis and is already cross-linked.
  2. BIt is a fully cross-linked network that cannot be moulded.
  3. CIt is a linear, low-molar-mass phenol-formaldehyde prepolymer made with excess phenol under acid catalysis, and it is cross-linked later by adding more formaldehyde or hexamethylenetetramine.
  4. DIt is formed by chain-growth addition of phenol across the of formaldehyde without loss of water.

Answer: C

Excess phenol with acid gives novolac, linear chains joined by methylene bridges, still fusible and soluble. Curing needs extra formaldehyde or hexamine to build the cross-links. Excess formaldehyde with base gives the resole, which is a different prepolymer.
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