JEE Main levelSingle correct optionDifficulty 2 of 3pl030
A sample of polystyrene (repeat unit −[CHX2−CH(CX6HX5)]X−, taken as 104 gmol−1) has Mn=1.04×105gmol−1. The number-average degree of polymerisation is
A104
B500
C1000
D1.04×105
Answer: C
DPn=Mn/M0=1.04×105/104=1000 repeat units, since each styrene unit adds 104 to the chain mass.