JEE Advanced levelSingle correct optionDifficulty 3 of 3pl008
Terylene forms by esterification of ethylene glycol (HOCHX2CHX2OH) with terephthalic acid (benzene-1,4-dicarboxylic acid, HOOC−CX6HX4−COOH). Taking C = 12, H = 1, O = 16 and ignoring end groups, the molar mass of one repeat unit in gmol−1 is
A228
B210
C192
D174
Answer: C
Molar masses: glycol 62, terephthalic acid 166. One repeat unit uses one of each and two ester bonds are formed, so two HX2O (36) are lost: 62+166−36=192.