JEE Main levelSingle correct optionDifficulty 2 of 3ph091
Chlorine water is added dropwise to potassium iodide solution containing starch. First a blue colour appears. On adding a large excess of chlorine water the blue colour disappears because
AIX2 is further oxidised to HIOX3
BIX2 is reduced back to IX−
Cstarch is decomposed by HCl
DIX2 sublimes away
Answer: A
Initially ClX2+2IX−2ClX−+IX2 and iodine forms the blue starch complex. Excess chlorine oxidises iodine further: IX2+5ClX2+6HX2O2HIOX3+10HCl, which gives no colour with starch.