JEE Main levelSingle correct optionDifficulty 2 of 3ph067
Assertion (A): IFX7 is known but ClFX7 and BrFX7 are not.
Reason (R): The iodine atom is large enough to accommodate seven fluorine atoms around it.
ABoth A and R are true and R is the correct explanation of A
BA is false but R is true
CBoth A and R are true but R is not the correct explanation of A
DA is true but R is false
Answer: A
For an XXn′ compound the ratio of radii of X and X' limits n. Iodine is the largest halogen, so seven small F atoms can be packed around it, while Cl and Br are too small. Hence A and R are true and R explains A.