JEE Main levelSingle correct optionDifficulty 2 of 3pn044
The basicities of HX3POX2, HX3POX3, HX3POX4 and HX4PX2OX7 are, respectively,
A1, 2, 3 and 4
B3, 3, 3 and 4
C1, 3, 3 and 4
D2, 2, 3 and 4
Answer: A
Basicity equals the number of ionisable P-OH groups; P-H hydrogens are not acidic. HX3POX2 has 1 P-OH (and 2 P-H), HX3POX3 has 2 P-OH (and 1 P-H), HX3POX4 has 3 P-OH, and HX4PX2OX7 has 4 P-OH.