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NEET levelSingle correct optionDifficulty 1 of 3pn001

The first ionisation enthalpy of nitrogen is higher than that of oxygen mainly because

  1. Anitrogen has a smaller atomic radius than oxygen
  2. Bnitrogen has a higher nuclear charge than oxygen
  3. Cnitrogen has a half-filled, extra-stable configuration
  4. Dnitrogen is more electronegative than oxygen

Answer: C

Removing an electron from () disrupts a half-filled, exchange-stabilised subshell, whereas in () the paired electron is removed with relief of repulsion. Oxygen actually has the higher nuclear charge, the smaller radius and the higher electronegativity, so those are not the cause. Hence the half-filled configuration is the reason.
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