JEE Advanced levelSingle correct optionDifficulty 3 of 3pb044
Which statement about boron nitride, (BN)x, is correct?
AThe hexagonal form has sp2 B and N in layers and is an electrical insulator, while the cubic form (all sp3) is extremely hard
BThe cubic form is a soft lubricant with sp2 atoms
CThe hexagonal form is a good conductor of electricity like graphite
DIn the hexagonal form, both B and N are sp3 hybridised
Answer: A
BN is isoelectronic with C−C units. Hexagonal BN has graphite-like layers of sp2 B and N, but the π electrons are localised on the more electronegative N, so it is a white insulator. Cubic BN (diamond-like, sp3) is extremely hard.