JEE Main levelSingle correct optionDifficulty 2 of 3pb026
A little aqueous ammonia is added to a solution of potash alum, and then more ammonia is added in excess. What is observed?
ANo precipitate forms at any stage
BA white precipitate forms which dissolves in excess ammonia
CA blue precipitate forms
DA white gelatinous precipitate forms which does not dissolve in excess ammonia
Answer: D
AlX3++3NHX3+3HX2OAl(OH)X3+3NHX4X+ gives white gelatinous Al(OH)X3. Aluminium hydroxide is amphoteric but is not dissolved by the weak base ammonia, unlike Zn(OH)X2 which forms an ammine complex.