JEE Advanced levelSingle correct optionDifficulty 3 of 3o4140
Ethanal (2 mol) is treated with dilute NaOH and warmed. The organic product is then hydrogenated over Ni (excess HX2). The final product is
Abutan-2-ol
Bbutanal
Cbutane-1,3-diol
Dbutan-1-ol
Answer: D
Aldol addition gives 3-hydroxybutanal, which dehydrates by E1cB (via the enolate) to but-2-enal. Excess HX2/Ni reduces both C=C and C=O, giving CHX3CHX2CHX2CHX2OH, butan-1-ol.