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JEE Advanced levelSingle correct optionDifficulty 3 of 3o4140

Ethanal (2 mol) is treated with dilute and warmed. The organic product is then hydrogenated over (excess ). The final product is

  1. Abutan-2-ol
  2. Bbutanal
  3. Cbutane-1,3-diol
  4. Dbutan-1-ol

Answer: D

Aldol addition gives 3-hydroxybutanal, which dehydrates by E1cB (via the enolate) to but-2-enal. Excess /Ni reduces both and , giving , butan-1-ol.
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