Answer: A
The alkene is 3,3-dimethylbut-1-ene. Methyl shift in the cation gives 2-bromo-2,3-dimethylbutane as the major bromide. Dehydrohalogenation with alcoholic KOH follows Zaitsev's rule and gives the more substituted, tetrasubstituted alkene, 2,3-dimethylbut-2-ene.