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JEE Advanced levelSingle correct optionDifficulty 3 of 3o2091

2-Methylbutane is monochlorinated with and light. How many monochloro products are possible in total, counting all stereoisomers (enantiomers) as separate compounds?

  1. A7
  2. B5
  3. C4
  4. D6

Answer: D

Four constitutional isomers form. 1-chloro-2-methylbutane (stereocentre C-2) and 2-chloro-3-methylbutane (stereocentre C-2) are chiral and each exists as a pair of enantiomers. 2-chloro-2-methylbutane and 1-chloro-3-methylbutane are achiral. Total .
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