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JEE Advanced levelOne or more correct optionsDifficulty 3 of 3o2051

Select the correct statements about the peroxide-initiated addition of HBr to an alkene.

  1. AThe initiation step involves homolysis of the weak bond of the peroxide.
  2. B adds to the less substituted alkene carbon so that the more stable carbon radical forms.
  3. CThe carbon radical abstracts a hydrogen atom from HBr, regenerating .
  4. DA carbocation intermediate is formed when adds to the alkene.

Answer: A, B, C

Peroxide O-O homolysis starts the chain (statement 1). In propagation, adds to the less hindered carbon to give the more stable radical (2), and this radical abstracts H from HBr to give the product and a new (3). No carbocation is involved in a radical chain, so statement 4 is wrong.
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