Answer: D
2,3-Dimethylbut-1-ene and 2,3-dimethylbut-2-ene both protonate to the tertiary cation (CHX3)X2CX+−CH(CHX3)X2. 3,3-Dimethylbut-1-ene reaches it by a methyl shift. 4-Methylpent-1-ene gives a secondary cation with no stabilising 1,2-shift, so it gives 4-methylpentan-2-ol.