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JEE Main levelSingle correct optionDifficulty 2 of 3o1188

Which ethyl benzoate is hydrolysed fastest by aqueous NaOH?

  1. Aethyl benzoate
  2. Bethyl 4-methylbenzoate
  3. Cethyl 4-nitrobenzoate
  4. Dethyl 4-methoxybenzoate

Answer: C

The slow step is the attack of on the carbonyl carbon, forming a negatively charged tetrahedral intermediate. The strongly electron-withdrawing increases the electrophilicity of the carbonyl carbon and stabilises the intermediate, whereas and donate electrons.
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