NEET levelSingle correct optionDifficulty 1 of 3o1057
Acetaldehyde is treated with (i) CHX3MgBr in dry ether; (ii) HX3OX+. The product is
Apropan-2-ol
B2-methylpropan-2-ol
Cethanol
Dpropan-1-ol
Answer: A
The methyl carbanion of the Grignard reagent adds to the carbonyl carbon of CHX3CHO giving CHX3−CH(OMgBr)−CHX3. Hydrolysis gives the secondary alcohol CHX3−CH(OH)−CHX3, propan-2-ol.