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JEE Main levelSingle correct optionDifficulty 2 of 3o1032

In the Finkelstein reaction , acetone is the preferred solvent because

  1. Aacetone reacts with to remove it
  2. B dissolves in acetone but does not, so precipitation of drives the reaction forward
  3. C dissolves much better than in acetone
  4. Dacetone is protic and strongly activates iodide

Answer: B

Acetone is polar aprotic and dissolves the iodide, whose nucleophilicity is not damped by hydrogen bonding. Sodium chloride (and bromide) are poorly soluble in acetone and precipitate, so by Le Chatelier's principle the equilibrium is displaced to the alkyl iodide.
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