JEE Main levelSingle correct optionDifficulty 2 of 3o1028
In DMSO the nucleophilicity of the halide ions toward CHX3I follows the order
ABrX−>ClX−>FX−>IX−
BFX−>ClX−>BrX−>IX−
CIX−>BrX−>ClX−>FX−
DClX−>FX−>BrX−>IX−
Answer: B
DMSO is aprotic and does not hydrogen bond to anions, so solvation differences vanish and nucleophilicity follows basicity (charge density), i.e. FX−>ClX−>BrX−>IX−. This is the reverse of the order in protic solvents.