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JEE Main levelSingle correct optionDifficulty 2 of 3o1028

In DMSO the nucleophilicity of the halide ions toward follows the order

  1. A
  2. B
  3. C
  4. D

Answer: B

DMSO is aprotic and does not hydrogen bond to anions, so solvation differences vanish and nucleophilicity follows basicity (charge density), i.e. . This is the reverse of the order in protic solvents.
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