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NEET levelSingle correct optionDifficulty 1 of 3nc150

Aniline reacts with bromine water to give

  1. A4-bromoaniline only
  2. B2-bromoaniline only
  3. C2,4,6-tribromoaniline, a white precipitate
  4. D3-bromoaniline

Answer: C

The amino group is strongly activating and directs to the ortho and para positions. With bromine water substitution is so rapid that all three positions are brominated, giving a white precipitate of 2,4,6-tribromoaniline.
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