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JEE Main levelOne or more correct optionsDifficulty 2 of 3nc121

Which of the following statements about the basicity of amines are correct? (Use the standard aqueous orders for methyl and ethyl amines.)

  1. AIn water, is a stronger base than .
  2. BIn water, is a stronger base than .
  3. CIn the gas phase, is a stronger base than .
  4. DIn water, is a stronger base than .

Answer: A, B, C

Aqueous order for methylamines: , so (A) is true. For ethylamines the order is , so (B) is true. In the gas phase basicity rises with the number of alkyl groups, so (C) is true. Aniline is weaker than ammonia, so (D) is false.
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