JEE Advanced levelOne or more correct optionsDifficulty 3 of 3mc220
A hydrocarbon has a vapour density of 53 and contains 90.57% carbon by mass (C = 12, H = 1). Select the correct statement(s).
A1.06g of it contains 0.08 mol of carbon atoms.
BIts empirical formula is CX4HX5.
CIts empirical formula mass is 106.
DIts molecular formula is CX8HX10.
Answer: A, B, D
M = 2 x 53 = 106. In 100 g: C = 7.547 mol, H = 9.43 mol, ratio = 4 : 5, so the empirical formula is C4H5 (mass 53). n = 106/53 = 2 gives C8H10. 1.06 g = 0.0100 mol, containing 0.0100 x 8 = 0.08 mol C.