JEE Main levelNumerical answerDifficulty 2 of 3mc101
PClX5 dissociates as PClX5PClX3+ClX2 and is 40% dissociated at equilibrium. Taking P=31, Cl=35.5, find the vapour density of the equilibrium mixture, to two decimals.
Numerical answer type, tolerance 0.02.
Answer: 74.46
PClX5 = 31 + 177.5 = 208.5 g/mol. For 1 mol initially, moles at equilibrium = 1 + 0.4 = 1.4, mass unchanged. Average molar mass = 208.5/1.4 = 148.93; vapour density = 148.93/2 = 74.46.