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JEE Advanced levelOne or more correct optionsDifficulty 3 of 3mt161

Which statements about the Hall-Heroult process are correct?

  1. Afluorspar, , is added to lower the melting point and improve the fluidity of the melt
  2. Bthe overall cell reaction is
  3. Cliquid aluminium is liberated at the anode and floats on the melt
  4. Dthe steel tank lined with graphite acts as the cathode

Answer: A, B, D

The graphite-lined tank is the cathode where is reduced and the molten metal collects at the bottom. Fluorspar lowers the melting point. The overall reaction consumes graphite anodes giving . Aluminium is formed at the cathode, not at the anode, and being denser than the melt it sinks.
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