JEE Main levelSingle correct optionDifficulty 2 of 3mt130
Assertion (A): During the cyanide leaching of gold, air is bubbled through the mixture.
Reason (R): Oxygen oxidises gold to Au(I), which is stabilised as [Au(CN)X2]X−.
ABoth A and R are true and R is the correct explanation of A
BBoth A and R are true but R is not the correct explanation of A
CA is true but R is false
DA is false but R is true
Answer: A
4Au+8CNX−+OX2+2HX2O4[Au(CN)X2]X−+4OHX− shows that oxygen is the oxidant and cyanide is the ligand which shifts the Au(I)/Au potential. Without air gold would not dissolve, so both statements are true and R explains A.