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JEE Main levelSingle correct optionDifficulty 2 of 3mt076

Chromium(III) oxide is reduced by aluminium rather than by carbon in the metallurgy of chromium. Which Ellingham-based statement supports aluminium?

  1. AAluminium is a gas at the working temperature
  2. BThe line of has a negative slope
  3. CAt the working temperature the line of lies below the line of , so of is negative
  4. DThe line of lies above that of

Answer: C

An element can reduce the oxide of another if its own oxide line lies lower on the Ellingham diagram. The line is below that of , so the coupled reaction has a negative . Hence aluminothermy works.
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