JEE Main levelSingle correct optionDifficulty 2 of 3mt076
Chromium(III) oxide is reduced by aluminium rather than by carbon in the metallurgy of chromium. Which Ellingham-based statement supports aluminium?
AAluminium is a gas at the working temperature
BThe line of AlX2OX3 has a negative slope
CAt the working temperature the line of AlX2OX3 lies below the line of CrX2OX3, so ΔG∘ of CrX2OX3+2AlAlX2OX3+2Cr is negative
DThe line of AlX2OX3 lies above that of CrX2OX3
Answer: C
An element can reduce the oxide of another if its own oxide line lies lower on the Ellingham diagram. The AlX2OX3 line is below that of CrX2OX3, so the coupled reaction has a negative ΔG∘. Hence aluminothermy works.