JEE Advanced levelSingle correct optionDifficulty 3 of 3nm204
Saturated open-chain carbonyl compounds (aldehydes and ketones) of formula CX5HX10O are considered. How many of them give a positive Tollens' test or a positive iodoform test (or both)? Structural isomers only.
A6
B2
C5
D7
Answer: A
There are 4 aldehydes (all Tollens-positive) and 3 ketones: pentan-2-one and 3-methylbutan-2-one are methyl ketones (iodoform-positive), pentan-3-one is not. No aldehyde C5 isomer contains CH3CO. Hence 4 + 2 = 6 compounds qualify.