MolSynapsequestion bank
MolSynapse / Question bank / IUPAC Nomenclature and Structural Isomerism / Counting structural isomers
JEE Advanced levelSingle correct optionDifficulty 3 of 3nm204

Saturated open-chain carbonyl compounds (aldehydes and ketones) of formula are considered. How many of them give a positive Tollens' test or a positive iodoform test (or both)? Structural isomers only.

  1. A6
  2. B2
  3. C5
  4. D7

Answer: A

There are 4 aldehydes (all Tollens-positive) and 3 ketones: pentan-2-one and 3-methylbutan-2-one are methyl ketones (iodoform-positive), pentan-3-one is not. No aldehyde C5 isomer contains CH3CO. Hence 4 + 2 = 6 compounds qualify.
Practice IUPAC Nomenclature and Structural Isomerism More on Counting structural isomers

More questions on Counting structural isomers