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Which of the following alkanes give exactly three different monochloro derivatives (structural isomers) on free-radical chlorination?

  1. An-Hexane
  2. B2-Methylpentane
  3. C2,2-Dimethylbutane
  4. D3-Methylpentane

Answer: A, C

Count distinct H environments: n-hexane 3, 2-methylpentane 5, 2,2-dimethylbutane 3, 3-methylpentane 4. Exactly three: A, C.
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