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IUPAC Nomenclature and Structural Isomerism
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Counting structural isomers
JEE Main level
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nm196
Which of the following alkanes give exactly three different monochloro derivatives (structural isomers) on free-radical chlorination?
A
n-Hexane
B
2-Methylpentane
C
2,2-Dimethylbutane
D
3-Methylpentane
Answer: A, C
Count distinct H environments: n-hexane 3, 2-methylpentane 5, 2,2-dimethylbutane 3, 3-methylpentane 4. Exactly three: A, C.
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