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IUPAC Nomenclature and Structural Isomerism
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Counting structural isomers
JEE Main level
Single correct option
Difficulty 2 of 3
nm178
2,2,4-Trimethylpentane (isooctane),
(
CH
X
3
)
X
3
C
−
CH
X
2
−
CH
(
CH
X
3
)
X
2
, is monochlorinated. The number of structural isomers of the product
C
X
8
H
X
17
Cl
is
A
3
B
4
C
5
D
6
Answer: B
Distinct H types: the three methyls of the tert-butyl group (1), the
CH
X
2
(2), the
CH
(3), and the two equivalent methyls on that CH (4). So 4.
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