MolSynapsequestion bank
MolSynapse / Question bank / IUPAC Nomenclature and Structural Isomerism / Nomenclature of bicyclic, spiro and aromatic compounds
JEE Advanced levelSingle correct optionDifficulty 3 of 3nm150

with the two substituents para on the ring is correctly named

  1. A4-nitro-N-methylaniline
  2. BN-methyl-3-nitroaniline
  3. C1-(methylamino)-4-nitrobenzene
  4. DN-methyl-4-nitroaniline

Answer: D

The amine is senior to the nitro group (which is only ever a prefix), so the parent is aniline with the N-bearing carbon as C-1. Substituents are: methyl on nitrogen (locant N) and nitro at C-4 (para). Alphabetically methyl precedes nitro: N-methyl-4-nitroaniline.
Practice IUPAC Nomenclature and Structural Isomerism More on Nomenclature of bicyclic, spiro and aromatic compounds

More questions on Nomenclature of bicyclic, spiro and aromatic compounds