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JEE Main levelSingle correct optionDifficulty 2 of 3nm036

Isopropyl is named systematically as 1-methylethyl. What is the IUPAC name of , using that prefix?

  1. A4-(1-methylethyl)octane
  2. B4-(2-methylethyl)octane
  3. C5-(1-methylethyl)octane
  4. D4-(1,1-dimethylethyl)octane

Answer: A

The longest chain runs through the propyl and butyl portions and has eight carbons (octane); the isopropyl group is a substituent. Numbering from the propyl end places the substituent at C4, while numbering from the butyl end places it at C5, so the lower locant 4 is chosen. The prefix is (1-methylethyl), so the name is 4-(1-methylethyl)octane.
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