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Ionic Equilibrium I
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pH of strong and weak acids and bases, mixtures
JEE Main level
One or more correct options
Difficulty 2 of 3
ie088
Consider P:
0.01
M
HCl
; Q:
0.005
M
H
X
2
SO
X
4
; R:
0.01
M
NaOH
; S:
0.005
M
Ba
(
OH
)
X
2
(all strong, fully ionised, 298 K). Select the correct statement(s). (Use
lo
g
5
=
0.699
.)
A
Mixing 1 volume of P with 3 volumes of R gives pH 11.70.
B
The pH of S is 11.70.
C
Equal volumes of Q and R give a neutral solution.
D
P and Q have the same pH, equal to 2.
Answer: A, C, D
P:
[
H
X
+
]
=
0.01
; Q:
[
H
X
+
]
=
0.01
, both pH 2. S:
[
OH
X
−
]
=
0.01
, pH 12 (so 11.70 is wrong). Q + R equal volumes:
H
X
+
=
OH
X
−
, neutral. P:R = 1:3: excess
OH
X
−
=
(
3
−
1
)
×
0.01/4
=
5
×
1
0
−
3
, pOH
2.30
, pH
11.70
.
Practice Ionic Equilibrium I
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