JEE Advanced levelNumerical answerDifficulty 3 of 3ie034
100mL of 0.1MHCl and 200mL of 0.05MHX2SOX4 (treat both protons as completely ionised) are mixed with 100mL of 0.28MNaOH. Find the pH to two decimals (log5=0.699).
Numerical answer type, tolerance 0.01.
Answer: 2.3
n(HX+)=10+20=30mmol; n(OHX−)=28mmol. Excess HX+=2mmol in 400mL gives [HX+]=0.005M and pH=2.301≈2.30.