JEE Main levelOne or more correct optionsDifficulty 2 of 3ia197
Equal volumes of 0.10MCHX3COOH (pKa=4.76) and 0.10MNHX3 (pKb=4.74) are mixed. Using pH=7+21(pKa−pKb) for the salt of a weak acid and a weak base, select the correct statement(s).
AThe solution is clearly acidic (pH below 6) because acetic acid is the stronger acid
BThe pH of the resulting CHX3COONHX4 solution is about 7.01
CIf HCN (pKa=9.20) replaced acetic acid, the pH of the salt would be about 9.23
DThe pH is independent of the salt concentration
Answer: B, C, D
Acid and base are mixed in equal moles, giving CHX3COONHX4: pH=7+(4.76−4.74)/2=7.01. The expression has no concentration term. The two constants are nearly equal, so the solution is almost neutral. For NHX4CN: 7+(9.20−4.74)/2=9.23.