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JEE Advanced levelOne or more correct optionsDifficulty 3 of 3ia163

The following concern AgCl () and (). Take the solubility in as and in water as . Which statements are correct?

  1. AThe solubility in is more than 300 times that in water.
  2. BIn the saturated ammoniacal solution, is about , far below its value in water.
  3. CIn the saturated ammoniacal solution, exceeds .
  4. DAdding dilute to the clear ammoniacal solution can re-precipitate AgCl.

Answer: A, B, D

Ratio . In the ammoniacal solution (vs in water), so it is not above . Acid protonates to , the complex dissociates and AgCl precipitates again.
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