JEE Advanced levelNumerical answerDifficulty 3 of 3ig047
A mixture of NX2 (molar mass 28) and COX2 (molar mass 44) has a density of 1.600gL−1 at 300K and 1.00atm. Taking R=0.0821LatmK−1mol−1, the mole percent of COX2 in the mixture (one decimal) is
Numerical answer type, answer in %, tolerance 0.2.
Answer: 71.3 %
Average molar mass Mˉ=PdRT=1.600×0.0821×300=39.408gmol−1. With x the mole fraction of COX2: 28(1−x)+44x=39.408, x=1639.408−28=0.7130, i.e. 71.3 mole percent.