JEE Advanced levelSingle correct optionDifficulty 3 of 3hc183
Aqueous sodium succinate, NaOOC−CHX2−CHX2−COONa, is electrolysed (Kolbe conditions). The hydrocarbon formed at the anode is:
AEthene
BButane
CEthane
DCyclobutane
Answer: A
Both carboxylates are oxidised and lose COX2 to form a diradical ⋅CHX2−CHX2⋅, which gives the alkene CHX2=CHX2. The total anode gas is ethene and COX2.