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JEE Main levelSingle correct optionDifficulty 2 of 3hc082

Which sequence is the best way to prepare pent-2-yne from propyne?

  1. A(i) ; (ii)
  2. B(i) (aq); (ii)
  3. C(i) ; (ii)
  4. D(i) ; (ii)

Answer: D

Sodamide converts propyne to sodium propynide, , which attacks a primary alkyl halide in an reaction. With the product is , pent-2-yne. Aqueous NaOH is too weak a base, methyl bromide would give but-2-yne, and a tertiary halide gives elimination instead.
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