MolSynapsequestion bank
MolSynapse / Question bank / Haloalkanes and Haloarenes / KCN vs AgCN, KNO2 vs AgNO2, Finkelstein and Swarts on drawn halides
JEE Main levelOne or more correct optionsDifficulty 2 of 3hx262

The halide shown is treated with the reagent named in each option, and the structure drawn is claimed to be the main product. Select all options in which the pairing is correct (textbook convention).

  1. AStructure A, using alcoholic
  2. BStructure B, using alcoholic
  3. CStructure C, using
  4. DStructure D, using

Answer: A, C

Alcoholic KCN is ionic and attacks through carbon, so the product is the nitrile (A is correct; B pairs KCN with the isocyanide, which is the AgCN product). AgNO2 gives the nitro compound through N (C is correct), whereas the nitrite ester drawn in D is the KNO2 product.
Practice Haloalkanes and Haloarenes More on KCN vs AgCN, KNO2 vs AgNO2, Finkelstein and Swarts on drawn halides

More questions on KCN vs AgCN, KNO2 vs AgNO2, Finkelstein and Swarts on drawn halides