MolSynapsequestion bank
MolSynapse / Question bank / Haloalkanes and Haloarenes / Grignard reagent products from drawn halides
JEE Advanced levelOne or more correct optionsDifficulty 3 of 3hx248

The Grignard reagent is prepared from the halide shown in dry ether. Each reaction is followed by work-up. Select all correct statements.

  1. AReaction with water gives methoxybenzene (anisole).
  2. BReaction with gives 4-methoxybenzoic acid.
  3. CReaction with propanone gives a secondary alcohol.
  4. DReaction with ethylene oxide gives 2-(4-methoxyphenyl)ethanol.

Answer: A, B, D

The aryl Grignard (4-methoxyphenylmagnesium bromide) is protonated by water to give anisole, adds to CO2 to give 4-methoxybenzoic acid, and opens ethylene oxide to give 2-(4-methoxyphenyl)ethanol. Acetone is a ketone and gives a tertiary alcohol, not a secondary one, so that statement is wrong.
Practice Haloalkanes and Haloarenes More on Grignard reagent products from drawn halides

More questions on Grignard reagent products from drawn halides