JEE Main levelSingle correct optionDifficulty 2 of 3hx208
(R)-Butan-2-ol is treated with SOClX2 alone, without pyridine (SNi mechanism with retention). The product is
Aracemic 2-chlorobutane
B(R)-2-chlorobutane
Cbut-2-ene
D(S)-2-chlorobutane
Answer: B
In SNi the chlorosulfite collapses with Cl delivered to the same face, so the configuration is retained. Priority order is OH > CX2HX5 > CHX3 > H and Cl > CX2HX5 > CHX3 > H, so the label remains R.