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JEE Main levelOne or more correct optionsDifficulty 2 of 3hx177

Select the correct statements about Grignard reagents .

  1. AA Grignard reagent can be safely prepared with methanol as the solvent.
  2. B forms a Grignard reagent more readily than .
  3. CThe carbon attached to magnesium carries a partial negative charge.
  4. DDiethyl ether stabilises the reagent by donating oxygen lone pairs to magnesium.

Answer: B, C, D

Iodides react fastest because of the weaker C-I bond; ether oxygen lone pairs solvate Mg; the C-Mg bond is polarised towards carbon. Methanol has an acidic O-H and would destroy the reagent.
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