JEE Advanced levelSingle correct optionDifficulty 3 of 3hx052
Optically pure (R)-2-halo compound reacts to give a product that is 70% inverted and 30% retained in spatial arrangement (an SN1 reaction with partial ion-pair shielding). The enantiomeric excess of the product, in favour of the inverted enantiomer, is
A40%
B30%
C70%
D100%
Answer: A
Enantiomeric excess = (major − minor) =70%−30%=40%. Equivalently, 60% of the product is racemic (30% of each enantiomer) and the remaining 40% is the inverted enantiomer in excess.