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JEE Advanced levelSingle correct optionDifficulty 3 of 3hx052

Optically pure (R)-2-halo compound reacts to give a product that is 70% inverted and 30% retained in spatial arrangement (an reaction with partial ion-pair shielding). The enantiomeric excess of the product, in favour of the inverted enantiomer, is

  1. A40%
  2. B30%
  3. C70%
  4. D100%

Answer: A

Enantiomeric excess (major minor) . Equivalently, 60% of the product is racemic (30% of each enantiomer) and the remaining 40% is the inverted enantiomer in excess.
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