JEE Main levelSingle correct optionDifficulty 2 of 3hx010
Silver propanoate is refluxed with bromine in CClX4 (Hunsdiecker reaction). The organic product is
A1-bromopropane
B2-bromopropane
Cbromoethane
Dpropanoyl bromide
Answer: C
The silver salt CHX3CHX2COOAg reacts with BrX2 to give an acyl hypobromite which decarboxylates by a radical path: CHX3CHX2COOAg+BrX2CHX3CHX2Br+COX2+AgBr. The alkyl halide has one carbon less than the acid.