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JEE Advanced levelOne or more correct optionsDifficulty 3 of 3g3219

In the acid-catalysed hydrolysis of in water, the steps are: (1) ionisation to ; (2) capture by to give ; (3) loss of to give . Which statements are correct?

  1. AThe path has three transition states
  2. BThe tert-butyl cation lies at an energy maximum
  3. CThe path has two reactive intermediates
  4. DThe ionisation (step 1) is the rate-determining step

Answer: A, C, D

Two intermediates ( and the oxonium ion) lie in energy minima, and each of the three steps has one transition state. Ionisation has the highest barrier. The cation is an intermediate (a minimum), not a maximum.
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