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General Organic Chemistry III: Reaction Intermediates
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Reaction energy profiles, kinetic vs thermodynamic control
JEE Main level
Single correct option
Difficulty 2 of 3
g3185
For the isomerisation
K
T
at 298 K,
Δ
G
∘
=
−
5.50
kJ
mo
l
−
1
(
R
=
8.314
J
mo
l
−
1
K
−
1
). The mole percent of T in the equilibrium mixture is closest to
A
99%
B
9%
C
50%
D
90%
Answer: D
K
=
e
−
Δ
G
∘
/
RT
=
exp
(
5500/
(
8.314
×
298
))
=
9.21
. Mole fraction of T
=
K
/
(
1
+
K
)
=
90.2%
, which is about 90%.
Practice General Organic Chemistry III: Reaction Intermediates
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